Design of Dithiobenzoate RAFT Agent Bearing Hydroxyl Groups and Its Application in RAFT Polymerization for Telechelic Diol Polymers

نویسندگان

  • Keita Kinoshita
  • Yuta Mori
  • Taku Takami
  • Yusuke Uchida
  • Yoshihiko Murakami
چکیده

RAFT polymerization is attractive for its reliability, facile operation, and high tolerance to a wide variety of monomers, functional groups, solvents, and temperatures. Herein, we report the RAFT-based synthesis of well-defined polymers bearing hydroxyl groups at two terminals by using various monomers. We found that the molecular weight of obtained polymers was half that of a target value when a trithiocarbonate-type chain transfer agent (CTA) was used, suggesting that the polymers unexpectedly cleaved at the middle of the polymer chain as the reaction was proceeding. To address the problem, we synthesized a novel “dithiobenzoate”-type CTA, 2-[N-(2-hydroxyethyl)carbamoyl]prop-2-yl 4-hydroxydithiobenzoate (HECPHD), which bears hydroxyl groups at both terminals, and we succeeded in RAFT polymerization with various monomers without a cleavage of the polymers.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

A New Approach for Monte Carlo Simulation of RAFT Polymerization

In this work, based on experimental observations and exact theoretical predictions, the kinetic scheme of RAFT polymerization is extended to a wider range of reactions such as irreversible intermediate radical terminations and reversible transfer reactions. The reactions which have been labeled as kinetic scheme are the more probable existing reactions as the theoretical point of view. The ...

متن کامل

A Versatile Method To Prepare RAFT Agent Anchored Substrates and the Preparation of PMMA Grafted Nanoparticles

Well-defined polymer brushes grafted onto silica nanoparticles were prepared by reversible additionfragmentation chain transfer polymerization (RAFT). A versatile RAFT agent, 4-cyanopentanoic acid dithiobenzoate (CPDB), was attached to amino-functionalized colloidal silica nanoparticles by direct condensation of the mercaptothiazoline-activated CPDB with the surface amino groups. RAFT polymeriz...

متن کامل

Geotechnical Interaction of Piled Raft Foundations: Two Case Studies

Application of pile-raft foundations, which are known as “compound foundations”, is a suitable alternative in the case of heavy load structures. The interaction behavior of pile raft foundations makes these systems very complex to analyze. Different methods have been proposed to determine the bearing capacity of piled raft systems and distribution of loads between the components, i.e. pile grou...

متن کامل

A triple carboxylic acid-functionalized RAFT agent platform for the elaboration of well-defined telechelic 3-arm star PDMAc.

This communication describes the synthesis of a triple acid-functionalized RAFT agent and its use to prepare well-defined 3-arm star polymers of N,N-dimethylacrylamide (DMAc). A simple esterification reaction allowed the convenient integration of three electron-rich naphthalene recognition units on the RAFT agent platform and subsequently the elaboration of a naphthalene end-decorated telecheli...

متن کامل

Geotechnical Interaction of Piled Raft Foundations: Two Case Studies

Application of pile-raft foundations, which are known as “compound foundations”, is a suitable alternative in the case of heavy load structures. The interaction behavior of pile raft foundations makes these systems very complex to analyze. Different methods have been proposed to determine the bearing capacity of piled raft systems and distribution of loads between the components, i.e. pile grou...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2017